| Good
news for you: CRYSTECH Inc. have gotten the license of BIBO
patent in USA from FEE LICENSE
Introduction
BIBO (BiB3O6)
is a newly developed Nonlinear Optical Crystal. It has advanced characteristic for
the NLO application
broad transparency range from 286nm to 2500nm;
high optical homogeneity (dn»10-6/cm)
and being free of inclusion;
large effective SHG coefficient (about 9 times that of KDP);
high damage threshold;
Wide temperature-bandwidth
Inertness with respect to moisture
Structural
and Physical Properties
|
Crystal
Structure
|
Monoclinic,
point group 2
|
|
Lattice
parameters
|
a
= 7.116 Å, b = 4.993 Å, c = 6.508 Å
Z =2, b=105.5868¡ã
|
|
Melting
point (congruent)
|
726°
C
|
|
Hardness
|
5
- 5.5 mohs
|
|
Specific
heat |
0.5
J/gm-K at 330 K |
|
Thermal
expansion |
(4.8E-5[X],
4.4E-6[Y], -2.69E-5[Z]) |
|
Density
|
5.033
g/cm^3
|
|
Long
term stability
|
Insensitive
to moisture
|
Optical
properties
| Transmission range |
286- 2500 nm |
| NLO
coefficients |
d12=d14=2.3,
d25=d36=2.4, d11=2.53,
d13=-1.3,
d35=-0.9, d26=2.8 pm/V |
| Refractive Indices |
539.75 nm |
n1 =
1.9620, |
n2 =
1.7874, |
n3 =
1.8190 |
| 1079.5 nm |
n1 =
1.9166, |
n2 =
1.7569 |
n3 =
1.7835 |
Sellmeier Equations
|
|
| |
n12=3.6545+0.0511/(l2-0.0371)-0.0226l2
|
| |
n22=3.0740+0.0323/(l2-0.0316)-0.01337l2
|
| |
n32=3.1685+0.0373/(l2-0.0346)-0.01750l2 |
BIBO's
applications
SHG for middle and high power Nd: lasers at 1064nm
SHG of high power Nd: lasers at 1342nm & 1319nm
for red and blue laser
SHG for the Nd: Lasers at 914nm & 946nm for blue
laser.
Optical Parametric Amplifiers (OPA) and Oscillators
(OPO) application;
Over 2.8W cw 473nm blue output was achieved with
type I BIBO for frequency doubling 4.6W cw Nd:YAG pumped
by LD
Nonlinear
Optical Properties Compare (SHG@946nm)
| Crystals
|
Length
(mm) |
Deff
(pm/V) |
Walk-off
(mrad) |
Output Power(W)
|
Conv. Eff. |
| BIBO |
10.4 |
3.3 |
40.7 |
2.8 |
63% |
| LBO |
10 |
0.81 |
11.3 |
1.52 |
33% |
| BBO |
8 |
2.0 |
60.3 |
2.1 |
47% |
BIBO's
Specification
Transmitting wavefront distortion: less
than l/8 @ 633nm
Dimension tolerance: (W ± 0.1mm)
x (H ± 0.1mm) x (L + 0.2mm/-0.1mm)
Flatness: l/8 @ 633nm
Scratch/Dig code: 10/5 to MIL-O-13830A
Parallelism: better than 20 arc seconds
Perpendicularity: 5 arc minutes
Angle tolerance: Dq < ± 0.3°,
Df < ±0.3°
Quality Warranty Period: one year under
proper use
Crystech
Warrant:
Strict quality control;
High inside quality without any defection.
Large crystal size up to 20x20x40mm3
High damage AR-coating
Large quantity standard products in-stock
Fast delivery. (1-2 weeks ARO )
Standard Products
| Part
No. |
Dimension
|
Application
|
Coating
|
Type
|
| BIBO1305
|
3x3x5mm
|
SHG
or THG |
AR
coating |
I
|
| BIBO1307
|
3x3x7mm
|
SHG
or THG |
AR
coating |
I
|
| BIBO1310
|
3x3x10mm
|
SHG
or THG |
AR
coating |
I
|
| BIBO1410
|
4x4x10mm
|
SHG
or THG |
AR-coating
|
I
|
Nd:YAG Produces 2.8 W of Blue
Light
Researchers at the Institut für Laser
Physik at Universität Hamburg in Germany have set a
record for blue CW power generated from a diode-pumped solid-state
laser, using a new nonlinear crystal, BiB 3 O 6 (BiBO),
to frequency-double the 946-nm line of the Nd:YAG (Figure
1). The intracavity frequency-doubled laser produced up
to 2.8 W of 473-nm light when it was pumped with 21 W of
808-nm radiation from a diode laser, an approach that may
lead to more efficient, less expensive blue lasers in the
commercial market.
Figure
1. Researchers at Universität Hamburg have set a record
for the generation of blue light from a diode-pumped solid-state
laser. The 946-nm laser's mirrors had
low reflectivity at 1064 nm to suppress the Nd:YAG's stronger
line at that wavelength. The 946-nm transition terminates
on the upper Stark-split branch of the ground state, which
is approximately 0.7 percent populated at room temperature.
This quasi-three-level behavior causes laser photons to
be reabsorbed by the ground level in the unpumped regions
of the laser rod. To prevent this reabsorption, the researchers
matched the longitudinal pump beam very closely to the intracavity
laser mode.
Figure 2. The laser produced 4.6 W of 946-nm radiation in
the initial configuration (a). With an intracavity frequency-doubling
crystal of LBO, BBO or BiBO (b), the setup yielded 1.5,
2.1 or 2.8 W of 473-nm light, respectively. Type
I phase-matching in nonlinear crystal requires
that the laser be linearly polarized. But because thermal
gradients in the laser rod are circularly symmetric, the
rod's thermal birefringence is in polar coordinates. That
is, the fast and slow axes have different orientations at
different locations across the rod's cross section, so linearly
polarized light passing through the rod becomes depolarized.
This intracavity depolarization loss can seriously diminish
the output power.
Other researchers had shown that placing
a quarter-wave plate between the laser rod and the back
mirror will cause the worst parts of the depolarization
to be reversed on a second passage through the rod. The
Hamburg group borrowed this simple trick to boost its laser's
output by more than 25 percent.
In the arrangement used in the experiment,
the laser produced 4.6 W of polarized 946-nm output in the
configuration that included a 3.3 percent output coupler
for that wavelength (Figure 2, a). When the output mirror
was replaced with a high-reflection mirror for both the
IR and blue wavelengths and a BiBO crystal was placed in
the resonator (Figure 2, b), blue output of 2.8 W was obtained
through the second curved folding mirror, which was highly
transmissive at 473 nm.
The group also experimented with two better-known
nonlinear crystals in this second configuration. A 10-mm-long
LiB 3 O 5 (LBO) crystal produced 1.5 W, and an 8-mm-long
ß-BaB 2 O 4 (BBO) crystal produced 2.1 W. The 10.4-mm-long
BiBO crystal produced the record-setter. |