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Crystals Laser Crystals Ti : Sapphire

Introduction
Titanium-doped sapphire (Ti:sapphire) crystals combine supreme physical and optical properties with broadest lasing range. It's indefinitely long stability and useful lifetime added to the lasing over entire band of 660-1050 nm challenge "dirty" dyes in variety of applications. Medical laser systems, lidars, laser spectroscopy, direct femtosecond pulse generation by Kerr-type mode-locking - there are few of existing and potential applications.
The absorption band of Ti:Sapphire centered at 490 nm makes it suitable for variety of laser pump sources - argon ion, frequency doubled Nd:YAG and YLF, copper vapour lasers. Because of 3.2 µs fluorescence lifetime Ti:Sapphire crystals can be effectively pumped by short pulse flashlamps in powerful laser systems.

CRYSTECH have successfully produced large-sized (Dia.120x80mm) Ti:Sapphire by using the growth method of Temperature Gradient Technique (TGT). TGT is characterized by the capabilities of growing (0001) oriented sapphire with high doping level (a490=7.5cm-1) high gain, and high laser damage threshold. Pulsed, quasi-cw, cw, ps and fs lasing with high efficiency have been realized using TGT grown Ti: Sapphire. It can also meet current application such as in large aperture amplifiers for high power generation and laser fusion etc.

Basic Properties:

Chemical formula:

Ti3+: Al2O3

Crystal structure:

Hexagonal a=4.758, c=12.991

Density:

3.98 g/cm3

Melting point:

2040oC

Mohs hardness:

9

Thermal conductivity:

52 W/m/k

Laser action:

4-Level Vibronic

Fluorescence lifetime:

3.2m s (T=300K)

Tuning range:

660 - 1050 nm

Absorbtion range:

400 - 600 nm

Emission peak:

795 nm

Absorption peak:

488 nm

Refractive index:

1.76 @ 800 nm

Ti:Sapphire’s specifications:

Orientation:

Optical axis C normal to rod axis

Ti2O3 concentration:

0.06 - 0.5wt %

Figure Of Merit:

>250

End configurations:

Flat/Flat or Brewster/Brewster ends

Flatness:

l /10 @ 633 nm

Parallelism:

10 arc sec

Surface finishing:

10/5 scratch/dig to MIL-O-13830A

Wavefront distortion:

l /4 per inch

Note: AR Coating is available on request



 
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